منابع مشابه
Neutral tricoordinated beryllium(0) compounds--isostructural to BH(3) but isoelectronic to NH(3).
The electronic structure and reactivity of neutral tricoordinated Be(0) compounds BeL(3), L = CO (1), NHC (2) and PMe(3) (3) are explored by quantum mechanical calculations. These BeL(3) complexes are found to be planar or nearly planar like electron deficient BH3 but isoelectronic with NH3 and possess three L→Be donor-acceptor bonds. The Be atom can be considered as sp(2)-hybridized with a lon...
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In this research project, the nitrito nitro isomerization of [Co (NH3)5No2]F2 complex has been studied. Isomerization of this complex in the solid state follows a first order kinetics. The rate of isomerization at different temperatures was determined using a Fourier Transform Lnfrared Spectrophotometer. ? and ? are calculated at 298 K. The infrared, visible and ultraviolet spectra of th...
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We present the ab initio potential-energy surfaces of the NH–NH complex that correlate with two NH molecules in their 3 − electronic ground state. Three distinct potential-energy surfaces, split by exchange interactions, correspond to the coupling of the SA=1 and SB=1 electronic spins of the monomers to dimer states with S=0, 1, and 2. Exploratory calculations on the quintet S=2 , triplet S=1 ,...
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Rotationally resolved infrared spectra of the ν1 and ν3 N-H stretching vibrations of the Ar-NH2 radical ionic complex have been observed by means of photodissociation spectroscopy. The analysis of the rotational structure shows that the complex has a 3Σground electronic state with a linear or quasi-linear proton-bound structure Ar-H-N-H+ characterized by an intermolecular center of mass separat...
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2020
ISSN: 0044-2313,1521-3749
DOI: 10.1002/zaac.202000210